Name | zirconyl nitrate |
Synonyms | zirconyl nitrate ZIRCONYL NITRATE Dusicnan zirkonicity ZIRCONIUM OXYNITRATE bis(nitrato)oxozirconium ZIRCONIUM DINITRATE OXIDE Zirconyl nitrate solution zirconium dinitrate oxide Zirconium, bis(nitrato-kappaO)oxo- Zirconium (IV) oxynitrate dihydrate |
CAS | 13826-66-9 |
EINECS | 237-529-3 |
InChI | InChI=1/2HNO3.O.Zr/c2*2-1(3)4;;/h2*(H,2,3,4);;/r2HNO3.OZr/c2*2-1(3)4;1-2/h2*(H,2,3,4) |
Molecular Formula | N2O7Zr |
Molar Mass | 231.23 |
Density | 1.45g/mLat 25°C |
Boling Point | 83°C at 760 mmHg |
Water Solubility | 115g/L at 20℃ |
Vapor Presure | 49.8mmHg at 25°C |
Appearance | liquid |
Specific Gravity | 1.507 |
Use | Used as a reagent for the determination of potassium and fluoride, but also for the preparation of luminescent agents and refractory materials |
Risk Codes | R8 - Contact with combustible material may cause fire R34 - Causes burns |
Safety Description | S17 - Keep away from combustible material. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | UN 3098 5.1/PG 2 |
WGK Germany | 1 |
Hazard Class | 5.1 |
Packing Group | III |
White Crystal or powder. Deliquescence. Has a strong sour taste. Soluble in water, ethanol, aqueous solution is acidic. Thermal decomposition of toxic nitrogen oxide vapors.
zirconium hydroxide was dissolved in nitric acid and prepared by evaporation and crystallization.
reagents for the determination of potassium and fluoride. Can be used to dissolve insoluble lead, barium, strontium and calcium sulfate. It is also used in the manufacture of luminescent agents and refractory materials, as well as in the fields of electronics, instrumentation and metallurgical industry.
according to customer requirements. Moisture-proof and sealed storage. Contact with organic matter can burn and explosion. Risk code: GB 5.1 class 51524.
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Application | zirconium oxynitrate also forms zirconia dinitrate, which is an important chemical raw material, can be used as a reagent for the determination of potassium and fluoride, but also for the preparation of luminescent agents and refractory materials, but also for the preparation of catalysts, electronic products. used as a reagent for the determination of potassium and fluoride, but also for the preparation of luminescent agents and refractory materials |
preparation | (1) take 10.0 of zirconium oxychloride, add 100L of deionized water to dissolve, prepare 5wt%ZrO 2 solution. (2) the temperature is raised to 70 ° C., 8.62kg 30wt of liquid alkali is added dropwise to the salt solution of step (1), the pH value is adjusted to 9.0, the mixture is aged for 3H, left standing overnight, and solid-liquid separation is carried out. (3) the filter cake obtained in step (2) is added with deionized water (80L) for beating, 36g of ammonium nitrate is added, and the temperature is raised to 75 ° C. For 1H for solid-liquid separation. Repeat this step 3 times. (4) the filter cake obtained in step (3) is added to deionized water (80L) and then heated to 75 ° C. For 1H for solid-liquid separation. Repeat this step 1 time. (5) the filter cake obtained in step (4) is slurried with 5283G of 68wt% concentrated nitric acid solution, heated to 75 °c for 4H, completely dissolved, and solid-liquid separation. (6) the zirconium oxynitrate aqueous solution obtained in step (5) was rotary evaporated under vacuum for 8H to obtain a further concentrated zirconium oxynitrate aqueous solution. |
category | toxic substances |
toxicity grade | poisoning |
Acute toxicity | oral-rat LD50:2500 mg/kg; Intraperitoneal-rat LD50:1250 mg/kg |
explosive hazard characteristics | mixed with reductant, sulfur, phosphorus, etc, friction can burst |
flammability hazard characteristics | is combustible in combination with organic matter, reducing agent, combustible sulfur and phosphorus; toxic nitrogen oxides and zirconium-containing fumes from combustion |
storage and transportation characteristics | sealed, low temperature, dry |
fire extinguishing agent | water, sand, foam |
Occupational Standard | TWA5 mg (zirconium)/m3; STEL10 mg (zirconium)/M3 |